ENGLISH

科学研究

物理有机与绿色催化研究团队—张松林团队

发布日期:2018-12-07 15:21|浏览量:   来源:  

团队名称

物理有机与绿色催化研究团队

团队负责人

张松林副教授

张松林,男,1982年6月出生,博士,副教授,硕士生导师。1999年9月进入中国科学技术大学应用化学系学习,2004年7月获得中国科学技术大学应用化学专业理学学士学位和计算机科学与技术专业工学学士双学位。同年9月保研到中国科学技术大学化学系进行硕博连读,并于2010年7月获得中国科学技术大学有机化学专业理学博士学位,导师郭庆祥教授。期间于2007年10月到2008年10月,在国家留学基金委资助下,在日本东京大学化学系联合培养一年,导师是Eiichi Nakamura教授。2010年7月起至今,任职于江南大学化学与材料工程美高梅。

团队成员

朱振中副教授

朱振中,男,1963年6月出生,博士,副教授,硕士生导师。先后承担和完成了多项省、部级及企业研究课题,在国内外核心刊物上发表论文40多篇,申请发明专利20项(授权7项)。主编《仪器分析》教材一部。

团队介绍

本团队的研究兴趣是发展高效和绿色的过渡金属促进的有机反应,研究特色是实验研究与理论计算相结合,属于物理有机化学的范畴。这些研究取得了一些原创性的成果,在国际主流化学期刊包括J. Am. Chem. Soc., Org. Lett., Chem. Commun.J. Org. Chem.Dalton Trans.等发表了30余篇高质量的SCI论文,部分论文多次被原创和综述性论文所引用。本团队正在承担和已经完成国家自然科学基金面上和青年项目,江苏省自然科学青年基金,江苏省科技支撑项目和科技部国际合作项目等。部分研究成果获得了2015年度江苏省科学技术奖三等奖、无锡市科技进步奖二等奖和中国轻工业联合会科技进步奖二等奖。

科研成果

(一)近期论文:

1.Chang Xiao, Hai-Xing Wan andSong-Lin Zhang*. Regio- and Stereoselective Vicinal syn-Arylation-trifluoromethylation of Terminal Arylacetylenes.Asian J. Org. Chem.2018, accepted. DOI:10.1002/ajoc.201800432. Invited paper for a special issue on “Organofluorine Chemistry”.

2.Song-Lin Zhang*, Chang Xiao. Cu(III)-CF3complex enabled unusual (Z)-selective hydro-trifluoromethylation of terminal alkynes.J. Org. Chem.2018,83(18), 10908-10915. (IF: 4.805)

3.Song-Lin Zhang*, Chang Xiao and Hai-Xing Wan.Diverse copper(III) trifluoromethyl complexes with mono-, bi- and tridentate ligands and their versatile reactivity.Dalton Trans.,2018,47, 4779-4784. (IF: 4.099)

4.Song-Lin Zhang*, Hai-Xing Wan and Wen-Feng Bie, syn-Fluoro- and -Oxy-trifluoromethylation of Arylacetylenes.Org. Lett.,2017, 19(23), 6372-6375. (IF: 6.579)

5.Song-Lin Zhang*, Xian-Jin Wang and Ze-Long Yu. Chemoselective Access to γ-Ketoesters with Stereogenic Quaternary α-Center or γ-Keto Nitriles by Aerobic Reaction of α-Cyanoesters and Styrenes.Org. Lett.2017,19(12), 3139-3142. (IF: 6.579)

6.Song-Lin Zhang*, Hai-Xing Wan and Zhu-Qing Deng. A computational study on the mechanism of ynamide-mediated amide bond formation from carboxylic acids and amines.Org. Biomol. Chem.2017,15(30), 6367-6374. (IF: 3.564)

7.Xian-Jin Wang andSong-Lin Zhang*. Cyanation of aromatic/vinylic boronic acids with α-cyanoacetates.New J. Chem.2017, 41(24), 14826-14830. (IF: 3.269)

8.Song-Lin Zhang*and Zhu-Qin Deng.Synthesis and reductive elimination of arylPd(II) trifluoromethyl complexes: a remarkable concentration effect on chemoselectivity.Phys. Chem. Chem. Phys.2016,18(48), 32664-32667. (IF: 4.123)

9.Song-Lin Zhang* and Wen-Feng Bie, Ligand-dependent formation of ion-pair CuI/CuIII trifluoromethyl complexes containing bisphosphines.Dalton Transactions2016,45(44), 17588-17592.(IF: 4.029)----期刊back cover论文

10.Song-Lin Zhang* and Ze-Long Yu. C-C activation by retro-aldol reaction of two β-hydroxy carbonyl compounds: Synergy with Pd-catalyzed cross-coupling to access mono-α-arylated ketones and esters.J. Org. Chem.2016,81(1), 57-65. (IF: 4.849)

11.Song-Lin Zhang*and Zhu-Qin Deng.Copper-catalyzed retro-aldol reaction of β-hydroxy ketones or nitriles with aldehydes: chemo- and stereoselective access to (E)-enones and (E)-acrylonitriles.Org. Biomol. Chem.2016,14, 7282-7294.

12.Song-Lin Zhang*and Zhu-Qin Deng. Synthesis of quinolines and naphthyridines via catalytic retro-aldol reaction ofβ-hydroxyketones with ortho-aminobenzaldehydes or nicotinaldehydes.Org. Biomol. Chem.2016,14, 8966-8970.

13.Song-Lin Zhang* and Ze-Long Yu. Divergent synthesis of indoles, oxindoles, isocoumarins and isoquinolinones by general Pd-catalyzed retro-aldol/α-arylation.Org. Biomol. Chem.2016,14, 10511-10515.

14.Song-Lin Zhang* and Wen-Feng Bie. Isolation and characterization of copper(III) trifluoromethyl complexes and reactivity studies of aerobic trifluoromethylation of arylboronic acids.RSC Advances2016,6(75), 70902-70906.

15.Song-Lin Zhang*and Lu Huang. Copper-catalyzed cyanation of aryl iodides with

α-cyanoacetates via C–CN bond activation.Org. Biomol. Chem.2015,13(39), 9963-9968.—该期刊2015年第39期front cover论文.

16.Song-Lin Zhang*, Lu Huang and Li-Jun Sun. The mechanism, electronic and ligand effects for reductive elimination from arylPd(II) trifluoromethyl complexes: a systematic DFT study.Dalton Trans.2015,44(10), 4613-4622.---IF: 4.029.

17.Song-Lin Zhang*, Wen-Feng Bie and Lu Huang.Theoretical Insights into Mechanisms for Copper(I)-Catalyzed C-P Coupling of Diarylphosphines with Aryl Halides: A Combined Solvent and Ancillary Ligand Effect on the Identity of Active Catalyst and Reaction Mechanism.Organometallics2014,33, 5263-5271.—IF:4.186

18.Song-Lin Zhang*, Lu Huang and Wen-Feng Bie.Mechanism for Activation of the C-CN Bond of Nitriles by a Cationic CpRhIII-Silyl Complex: A Systematic DFT Study.Organometallics2014,33, 3030-3039.---IF: 4.186

19.Song-Lin Zhang*and Hui-Jun Fan. Theoretical Study on Copper-CatalyzedS-arylation of Thiophenols with Aryl Halides: Evidence Supporting the LCu(I)-SPh Active Catalyst and Halogen Atom Transfer Mechanism.Organometallics2013,32(17), 4944-4951.

20.Liang Li, Feng Wu,Songlin Zhang*, Dawei Wang, Yuqiang Ding* and Zhenzhong Zhu.A heteroleptic cyclometalated iridium(III) fluorophenylpyridine complex from partial defluorohydrogenation reaction : synthesis, photophysical properties and mechanistic insights.Dalton Trans.2013,42, 4539.

21.Songlin Zhang*, Zhenzhong Zhu and Yuqiang Ding, Proposal for Halogen Atom Transfer Mechanism for UllmannO-arylation of Aryl Halides with Phenols.Dalton Trans.2012,41, 13832.

22.Songlin Zhang*, Li Shi, Yuqiang Ding.Theoretical Analysis of the Mechanism of Pd(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of themeta-Regioselectivity.J. Am. Chem. Soc.2011.133, 20218.

23.Song-Lin Zhang,Yao Fu*, Rui Shang, Qing-Xiang Guo, Lei Liu*.Theoretical Analysis of Factors Controlling Pd-Catalyzed Decarboxylative Coupling of Carboxylic Acids with Olefins.J. Am. Chem. Soc.2010,132, 638.

24.Wei Yang,Songlin Zhang*, Yuqiang Ding*, Li Shi, Qijun Song. A Photoluminescent Dinuclear Phenylquinolyl Ir(II)-Ir(II) Complex Featuring a Phenylquinolyl Bridge and an End-on Dinitrogen Ligand.Chem. Commun.2011,47, 5310.

25.Songlin Zhang, Yuqiang Ding*. Theoretical Study on Mechanism of Copper(I)-Catalyzed Cross-Coupling between Aryl Halides and Alkylamines.Organometallics2011,30, 633.

(二)近期授权专利:

1.中国发明专利:制备聚醚酰胺材料的方法。ZL201210270136.5.授权日期:2013.12.25。

2.中国发明专利:具有吸湿和抗静电性能的聚醚胺改性尼龙材料的制备方法。ZL201310003523.7。授权日期:2014.09.03。

3.中国发明专利:胺基聚醚改性聚硅氧烷消泡剂的制备方法。ZL201310164057.0。授权日期:2015.8.12。

4、一种甲醛废气高效膜吸收技术 ZL200810196513.9

5、一种高浓度甲醛废气资源化处理方法 ZL200810196514.3

6、一种用于资源化处理甲醛废气的吸收剂 ZL201010288359.5

7、一种电化学测定乳液中氢过氧化物含量的方法 ZL2011 1042 5510.X

8、一种检测乳液或油脂氧化稳定性的方法 ZL2011 1042 4820.X

(三)承担的主要科研项目

1.2014年国家自然科学基金面上项目(21472068),名称:过渡金属催化的C-C单键活化反应的机理研究与新反应发展

2. 2012年国家自然科学基金青年项目(21202062),名称:钯催化的氟化和三氟甲基化反应机理的理论研究

3. 2012年江苏省自然科学基金青年项目(BK2012108),名称:过渡金属催化的氧化型C-H/C-H偶联反应机理的理论研究

4.中国博士后科学基金第52批面上资助项目(2012M520993),名称:聚醚胺材料的开发与应用

5.膜生物反应器处理生活污水的研究科技部国际合作重点项目

6.膜吸收高浓度甲醛废气资源化技术研究江苏省环境工程重点实验室开放基金

7.膜吸收法处理高浓度甲醛废气资源化技术江苏省科技支撑计划——社会发展项目

8.膜基吸收法高浓度氨氮废水资源化技术研究江苏省科技支撑计划——社会发展项目

联系方式:

通讯地址:江苏省无锡市蠡湖大道1800号,邮编214122

Email: slzhang@jiangnan.edu.cn(S.-L. Zhang)

zhuzhzh@jiangnan.edu.cn(Z. Zhu)

XML 地图 | Sitemap 地图