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Associate Professor

Songlin Zhang

2019-04-07  点击:[]

Dr. Song-Lin Zhang, Associate Professor of Chemistry at School of Chemical and Material Engineering, Jiangnan University.

Lihu Road 1800, Wuxi 214122, Jiangsu Province, China.

Tel: 86-510-85917763

E-mail: slzhang@jiangnan.edu.cn

Dr. Song-Lin Zhang was born in 1982 in Chizhou, Anhui Province. He obtained his Bachelor’s degree in Applied Chemistry in 2004 from University of Science & Technology of China (USTC), and continued his PhD study in USTC under the supervision of Prof. Qing-Xiang Guo and Prof. Lei Liu from Sept 2004 to June 2010. During Oct. 2007-Oc.2008, Dr. Zhang was sponsored by China Scholarship Council (CSC) to study in Department of Chemistry, the University of Tokyo under the supervision of Prof. Eiichi Nakamura. In June 2010, he obtained Doctor’s degree in Organic Chemistry from USTC, and then took a position as Associate Professor from July 2010 in School of Chemical and Material Engineering, Jiangnan University.

Zhang and coworkers’ research interests are focused on the development of new organic reactions by a combined experimental/computational study. Currently, two research programs have being launched in his group on developing novel C-C activation reactions and trifluoromethylation reactions. Their productive work has led to the publication of more than 30 high-quality papers in journals includingJ. Am. Chem. Soc.,Chem. Commun.,J. Org. Chem.,OrganometallicsandDalton Transactions. Their research activities are generally supported by theNational Natural Science Foundation of ChinaandNatural Science Foundation of Jiangsu Province. They are also financed by research funds granted by Jiangnan University. Dr. Zhang was awarded byDean Excellent Scholar of China Academy of Science(2010),“Zhishan”Young Scholar of Jiangnan Universityfrom 2014-2017, and also sharedScience and Technology Award of Jiangsu Province(2015).

Recent publications:

1.Song-Lin Zhang*and Zhu-Qin Deng.Synthesis and reductive elimination of arylPd(II) trifluoromethyl complexes: a remarkable concentration effect on chemoselectivity.Phys. Chem. Chem. Phys.2016,18(48), 32664-32667.

2.Song-Lin Zhang* and Wen-Feng Bie, Ligand-dependent formation of ion-pair CuI/CuIII trifluoromethyl complexes containing bisphosphines.Dalton Transactions2016,45(44), 17588-17592.

3.Song-Lin Zhang* and Ze-Long Yu. C-C activation by retro-aldol reaction of twoβ-hydroxy carbonyl compounds: Synergy with Pd-catalyzed cross-coupling to access mono-α-arylated ketones and esters.J. Org. Chem.2016,81(1), 57-65.

4.Song-Lin Zhang*and Zhu-Qin Deng.Copper-catalyzed retro-aldol reaction ofβ-hydroxy ketones or nitriles with aldehydes: chemo- and stereoselective access to (E)-enones and (E)-acrylonitriles.Org. Biomol. Chem.2016,14, 7282-7294.

5.Song-Lin Zhang*and Zhu-Qin Deng. Synthesis of quinolines and naphthyridines via catalytic retro-aldol reaction ofβ-hydroxyketones with ortho-aminobenzaldehydes or nicotinaldehydes.Org. Biomol. Chem.2016,14, 8966-8970.

6.Song-Lin Zhang* and Ze-Long Yu. Divergent synthesis of indoles, oxindoles, isocoumarins and isoquinolinones by general Pd-catalyzed retro-aldol/α-arylation.Org. Biomol. Chem.2016,14, 10511-10515.

7.Song-Lin Zhang* and Wen-Feng Bie. Isolation and characterization of copper(III) trifluoromethyl complexes and reactivity studies of aerobic trifluoromethylation of arylboronic acids.RSC Advances2016,6(75), 70902-70906.

8.Song-Lin Zhang*and Lu Huang. Copper-catalyzed cyanation of aryl iodides withα-cyanoacetates via C–CN bond activation.Org. Biomol. Chem.2015,13(39), 9963-9968.—2015年第39期封面论文.

9.Song-Lin Zhang*, Lu Huang and Li-Jun Sun. The mechanism, electronic and ligand effects for reductive elimination from arylPd(II) trifluoromethyl complexes: a systematic DFT study.Dalton Trans.2015,44(10), 4613-4622.

10.Song-Lin Zhang*, Wen-Feng Bie and Lu Huang.Theoretical Insights into Mechanisms for Copper(I)-Catalyzed C-P Coupling of Diarylphosphines with Aryl Halides: A Combined Solvent and Ancillary Ligand Effect on the Identity of Active Catalyst and Reaction Mechanism.Organometallics2014,33, 5263-5271.

11.Song-Lin Zhang*, Lu Huang and Wen-Feng Bie.Mechanism for Activation of the C-CN Bond of Nitriles by a Cationic CpRhIII-Silyl Complex: A Systematic DFT Study.Organometallics2014,33, 3030-3039.

12.Song-Lin Zhang*and Hui-Jun Fan. Theoretical Study on Copper-CatalyzedS-arylation of Thiophenols with Aryl Halides: Evidence Supporting the LCu(I)-SPh Active Catalyst and Halogen Atom Transfer Mechanism.Organometallics2013,32(17), 4944-4951.

13.Liang Li, Feng Wu,Songlin Zhang*, Dawei Wang, Yuqiang Ding* and Zhenzhong Zhu.A heteroleptic cyclometalated iridium(III) fluorophenylpyridine complex from partial defluorohydrogenation reaction: synthesis, photophysical properties and mechanistic insights.Dalton Trans.2013,42, 4539.

14.Songlin Zhang*, Zhenzhong Zhu and Yuqiang Ding, Proposal for Halogen Atom Transfer Mechanism for UllmannO-arylation of Aryl Halides with Phenols.Dalton Trans.2012,41, 13832.

15.Songlin Zhang*, Li Shi, Yuqiang Ding.Theoretical Analysis of the Mechanism of Pd(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of themeta-Regioselectivity.J. Am. Chem. Soc.2011.133, 20218.

16.Song-Lin Zhang,Yao Fu*, Rui Shang, Qing-Xiang Guo, Lei Liu*.Theoretical Analysis of Factors Controlling Pd-Catalyzed Decarboxylative Coupling of Carboxylic Acids with Olefins.J. Am. Chem. Soc.2010,132, 638.

17.Wei Yang,Songlin Zhang*, Yuqiang Ding*, Li Shi, Qijun Song. A Photoluminescent Dinuclear Phenylquinolyl Ir(II)-Ir(II) Complex Featuring a Phenylquinolyl Bridge and an End-on Dinitrogen Ligand.Chem. Commun.2011,47, 5310.

18.Songlin Zhang, Yuqiang Ding*. Theoretical Study on Mechanism of Copper(I)-Catalyzed Cross-Coupling between Aryl Halides and Alkylamines.Organometallics2011,30, 633.

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